S-to-O phosphoryl migration in the rhodium-catalyzed reaction of phosphorothioates with α-diazocarbonyl compounds: An access to tetrasubstituted enol phosphates
The aim is to explore the phosphoryl migration of phosphorothioates in reactions with α-diazocarbonyl compounds to access tetrasubstituted enol phosphates.
Utilized rhodium-catalysis to promote reactions between phosphorothioates and α-diazocarbonyl compounds.
Detailed mechanistic studies were performed to trace phosphoryl migration pathways.
Successfully synthesized tetrasubstituted enol phosphates through rhodium-catalyzed phosphoryl migration.
Characterized the reaction intermediates and confirmed the migration process via spectroscopic methods.