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May 3, 20260 citations

About the Role of Interfacial Lattice Oxygen in Pd─Pt Alloy for C─C Cleavage in Ethanol Electrooxidation.

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CZChunlin ZhuWZWeichen ZhangGZGenlei Zhang

Key Points

  • This work aims to redefine the role of interfacial lattice oxygen in Pd─Pt alloys for C─C cleavage during ethanol electrooxidation.
  • Introduction of an active mechanism for C─C cleavage in Pd─Pt alloy
  • Analysis of Faradaic efficiency related to ethanol electrooxidation
  • Achieved a C1-pathway Faradaic efficiency of 75.6%
  • Redefined heterointerfaces as programmable reaction-network architects

Abstract

and a C1-pathway Faradaic efficiency of 75.6%. This work reports a paradigm shift from a passive "scavenger" model to an active "initial-attack and system-orchestration" mechanism, redefining heterointerfaces as atomically programmable reaction-network architects. This paradigm offers a blueprint for mastering complex reaction networks, extending the frontier of rational catalyst design.

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Cite This Study

Zhu et al. (2026) studied this question.

synapsesocial.com/papers/69f6e67c8071d4f1bdfc7226https://doi.org/10.1002/anie.6830451
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