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May 6, 2026The Journal of Physical Chemistry Letters0 citations

Vacuum–Temperature Synergistic Effects on Phase Stability and Carrier Mobility of Lead-triiodide Perovskites

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CZChunyi ZhaoQZQiming ZhangJZJiancong Zheng

Key Points

  • This research examines the effects of vacuum and temperature on the phase stability and carrier mobility of lead-triiodide perovskites.
  • Investigated the phase stability under high vacuum conditions
  • Analyzed the thermal expansion coefficient at low pressure
  • Measured carrier diffusion length in simulated space environment
  • Lead-triiodide perovskites remain in the tetragonal phase around 78 K
  • Observed a significant reduction in thermal expansion under low pressure
  • Achieved carrier diffusion lengths of 10.2-14.9 μm in simulated space conditions

Abstract

under high vacuum exhibits an unusual compression behavior during phase transitions and remains in the tetragonal phase even around 78 K. This phase stability is attributed to a substantial drop in thermal expansion coefficient under low pressure. The material achieves a superior carrier diffusion length (10.2-14.9 μm) in the simulated space environment, surpassing its performance in terrestrial settings. These results provide new insight into the structural stability of perovskites and highlight their applicability across various conditions.

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Cite This Study

Zhao et al. (2026) studied this question.

synapsesocial.com/papers/69fa8eac04f884e66b53109bhttps://doi.org/10.1021/acs.jpclett.6c00702
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