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May 7, 2026ACS Applied Nano Materials3 citations

Metal Oxide Nanocrystals for UV Phototransistor: A Reduction Approach

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SDSandeep DahiyaAYAshok YadavSHSobhan Hazra

Key Points

  • The aim is to explore a scalable, low-cost synthesis of metal oxide nanocrystals for use in UV phototransistors.
  • Developed a solution-processed reduction method for synthesizing ZnO and SnO2 nanocrystals at low temperatures.
  • Integrated high-κ gate dielectric LiInSnO4 thin film to fabricate low-voltage thin-film transistors (TFTs).
  • Characterized the structural, morphological, and optical properties of NCs.
  • ZnO NC-based TFTs achieved field-effect mobility of 2.4 cm2.V–1.s–1 and an on/off ratio of ∼10^4.
  • SnO2 NC-based TFTs showed a mobility of 1.55 cm2.V–1.s–1 with an on/off ratio of 3 × 10^2.
  • Devices displayed significant UV photosensitivity, highlighting their applicability as photodetectors.

Abstract

Leveraging the exceptional optoelectronic properties of metal oxide nanocrystals (NCs), this study introduces a scalable technique of low-cost solution-processed reduction-based synthesis of ZnO and SnO2 nanocrystals through the reduction method at a low processing temperature, along with their detailed structural, morphological, and optical characterizations. Furthermore, these NCs have been utilized as a semiconductor channel with integration of a high-κ gate dielectric LiInSnO4 thin film to fabricate low-voltage operation thin-film transistors (TFTs). The achieved field-effect motilities of ZnO NC and SnO2 NC-based TFTs are 2.4 and 1.55 cm2.V–1.s–1, with their respective on/off ratios of ∼104 and 3 × 102, indicating their electronic grade applicability. Additionally, the devices exhibit pronounced ultraviolet (UV) photosensitivity, underscoring their potential as high-sensitivity UV photodetectors. Overall, the work demonstrates a facile, low-temperature synthesis strategy for metal oxide NCs, offering a scalable route toward next-generation optoelectronic platforms, including displays, integrated logic circuitry, advanced UV sensing architectures, and biointerfacing devices.

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Cite This Study

Dahiya et al. (2026) studied this question.

synapsesocial.com/papers/69fc2b608b49bacb8b347742https://doi.org/10.1021/acsanm.6c00808
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