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January 1, 2009Materials Research102 citationsOpen Access

Hydrothermal synthesis of well-crystallised boehmite crystals of various shapes

PSPérsio de Souza SantosACA. C. Vieira CoelhoHSHelena de Souza Santos

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Abstract

Aluminium monohydroxide, also known as aluminium oxyhydroxide (boehmite - AlOOH), is water insoluble but crystallises into microcrystals of various shapes. When, by X-ray diffraction, the microcrystals present a basal reflexion (d020) of 0.611 nm, the crystalline structure is referred to as "well-crystallised" boehmite. Natural and synthetic crystals of well-crystallised boehmite can have a plate-like shape with either a rhombic or hexagonal profile. Synthetic crystals can also be lath-like or ellipsoid in shape. The purpose of this paper is to present a method of hydrothermal synthesis using a single temperature (200 ºC) for preparing plate-like crystals of well-crystallised boehmite with ellipsoid, rhombic, hexagonal, and lath-like profiles by using different precursors. Our observations suggest that all of these shapes are stages of growth of the microcrystals of well-crystallised boehmite along the c-axis direction of the rhombic crystals.

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Cite This Study

Santos et al. (2009) studied this question.

synapsesocial.com/papers/69ffa13be4618ba4162d87bahttps://doi.org/10.1590/s1516-14392009000400012
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