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June 20, 2019Journal of the American Chemical Society94 citations

Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”

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OEOtega A. EjegbavwoCMCorey R. MartinOOOyindamola A. Olorunfemi

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Abstract

) for U- and Th-MOFs with 10- and 12-coordinated secondary building units (SBUs) were performed to elucidate experimentally observed transformations during the installation processes. Overall, these results are the first thermochemical, electronic, and mechanistic insights for a relatively young class of actinide-containing frameworks.

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Ejegbavwo et al. (2019) studied this question.

synapsesocial.com/papers/69ffec3010d6befb25775988https://doi.org/10.1021/jacs.9b04737
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