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May 12, 2026Journal of Materials Science Materials in Energy0 citationsOpen Access

Structure–property correlations in glycine-NaCl composites for possible bio-sensing application

ATArshiya TabassumBMBenson K. MoneyRMRupam Mukherjee

Key Points

  • To explore the effects of sodium chloride (NaCl) on the properties of glycine composites for possible bio-sensing applications.
  • Utilized UV–Vis spectroscopy to examine optical properties and absorption characteristics.
  • Conducted thermal analysis (TGA–DTA) to assess stability and phase transitions.
  • Performed dielectric measurements to analyze permittivity and conduction mechanisms.
  • Absorption edge showed a blue shift with altered optical transparency, indicating molecular–ionic interactions.
  • Dielectric measurements revealed enhanced permittivity (108) and significant dipolar and ionic contributions.
  • Nonlinear I-V characteristics indicated mixed ionic–electronic conduction with a hopping transport mechanism.

Abstract

We observe a significant influence of ionic incorporation on the structural, optical, thermal, and electrical properties of amino acid–based functional materials in Glycine: NaCl composites. UV–Vis spectroscopy revealed a blue shift in the absorption edge and modification of the optical transparency, indicating molecular–ionic interactions and defect-level formation. Thermal analysis (TGA–DTA) showed improved stability and altered phase-transition behavior, confirming that NaCl disrupts the hydrogen-bonding environment of glycine. Dielectric measurements exhibited enhanced permittivity (108), strong dispersion, and increased dielectric loss, attributed to dipolar, ionic, and Maxwell–Wagner interfacial polarization. The Cole-Cole plots confirmed non-Debye relaxation and distinct grain and grain-boundary contributions. Nonlinear I-V characteristics and temperature-dependent resistance measurements further evidenced mixed ionic–electronic conduction with hopping based transport mechanism, while heating–cooling resistance hysteresis revealed reversible microstructural and orientational changes. The results highlight Glycine: NaCl composites as promising candidates for low-power electronic components, thermal–electrical switching elements, and bio-compatible sensing applications. NaCl ions enhance charge transport in glycine composites. Composite exhibits dipolar dynamics and interfacial polarization. Ion assisted pathways reduce activation energy. Structure and temperature controls electrical and thermal performance. Promising for low power electronic devices.

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Cite This Study

Tabassum et al. (2026) studied this question.

synapsesocial.com/papers/6a02c2fdce8c8c81e9640558https://doi.org/10.1007/s44308-026-00016-3
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