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The title compound, (S)-C6H5C2H4NH3PbBr3, crystallizes as an organic–inorganic hybrid. As such, the structure consists of extended chains of PbBr3− units running along the a axis. Each Pb atom is octahedrally coordinated by six bromides, arranged as chains of face-sharing octahedra. These inorganic chains are separated by the isolated organic cations.
Billing et al. (2003) studied this question.