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February 18, 2022Angewandte Chemie International Edition78 citations

Sulfamide: A Promising Deep‐Ultraviolet Nonlinear Optical Crystal Assembled from Polar Covalent SO2(NH2)2 Tetrahedra

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HTHaotian TianNYNing YeMLMin Luo

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Abstract

] units was confirmed as an excellent candidate as a DUV NLO crystal. Sulfamide provides the optimal balance between composition, structure, and properties, in addition to a very short absorption of 160 nm. It achieves multiple optical performance records for non-π-conjugated DUV NLO materials, including the strongest second harmonic generation (SHG) efficiency (about 4 times that of KDP), the largest birefringence (obv.: 0.07@589.3 nm) and the shortest SHG wavelength predicted as 188 nm.

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Cite This Study

Tian et al. (2022) studied this question.

synapsesocial.com/papers/6a03b53394ec7ec37ca9ca19https://doi.org/10.1002/anie.202200395
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