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May 22, 2002Accounts of Chemical Research115 citations

Adhesion, Friction, and Mechanical Properties of Functionalized Alkanethiol Self-Assembled Monolayers

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JHJack E. HoustonHKHyun I. Kim

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Abstract

We have used interfacial force microscopy to study the adhesion, friction, and mechanical properties of molecular monolayers self-assembled on Au surfaces. This quantitative and stable scanning-probe technique permits detailed studies of these factors. By systematic variation of the chemical nature of the end groups on the monolayers and utilization of standard and intuitive contact-mechanics models, quantitative results are presented of inter- and intrafilm bonding strength as well as the relationship between mechanical behavior and the lateral friction force.

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Houston et al. (2002) studied this question.

synapsesocial.com/papers/6a03f8a6ac14ad449f2b3604https://doi.org/10.1021/ar9801144
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