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May 14, 2026Environmental Science and Pollution Research0 citationsOpen Access

Improving ozone-based processes for the degradation of paraquat and diquat as persistent pesticides

JSJoseph Soto‐VerjelPSPaula Serrano-TariSVSalvador Villamizar

Key Points

  • This research aims to enhance ozone-based processes for degrading persistent pesticides, particularly paraquat and diquat.
  • Conducted photocatalytic ozonation at a pilot scale to evaluate mineralization and contaminant removal rates.
  • Performed ecotoxicity assays using Aliivibrio fischeri to assess toxicity of transformation products.
  • Optimized ozone dosage and leverage renewable solar energy to minimize energy demand.
  • Photocatalytic ozonation achieved the highest mineralization rates and total contaminant removal.
  • Identified toxicity in transformation products generated at lower ozone dosages, necessitating optimized exposure times.
  • Significantly reduced energy demand for treatment by integrating solar radiation with ozonation.

Abstract

did not significantly improve the process; however, photocatalytic ozonation at a pilot scale achieved the highest mineralization rates and total contaminant removal. Ecotoxicity assays using Aliivibrio fischeri revealed toxicity in generated transformation products, particularly at lower ozone dosages, necessitating optimized exposure times to ensure safe effluent discharge. Furthermore, by leveraging renewable solar radiation and optimizing the ozone dosage, the overall energy demand is significantly reduced, offering a highly sustainable and cost-effective approach. This work demonstrates the effectiveness of integrated solar ozonation processes for the treatment of point-source herbicide contamination.

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Cite This Study

Soto‐Verjel et al. (2026) studied this question.

synapsesocial.com/papers/6a0567a8a550a87e60a1fc58https://doi.org/10.1007/s11356-026-37798-6
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