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March 10, 2020Angewandte Chemie International Edition127 citationsOpen Access

Visible‐Light‐Induced Palladium‐Catalyzed Generation of Aryl Radicals from Aryl Triflates

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MRMaxim RatushnyyNKNikita KvasovsSSSumon Sarkar

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Abstract

)-O bond, leading to hybrid aryl Pd-radical intermediates. The following 1,5-hydrogen atom translocation, intramolecular cyclization, and rearomatization steps lead to valuable oxindole and isoindoline-1-one motifs. Notably, this method provides access to products with readily enolizable functional groups that are incompatible with traditional Pd-catalyzed conditions.

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Ratushnyy et al. (2020) studied this question.

synapsesocial.com/papers/6a063cb3c00af984bd6ff63chttps://doi.org/10.1002/anie.201915962
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