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May 16, 2026Science4 citations

A molecular pathway to corrosion-resistant printable copper

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JZJ ZhangQZQiubo ZhangQFQikun Feng

Key Points

  • The research aims to develop a method for enhancing the corrosion resistance and conductivity of copper at lower temperatures.
  • Utilized a molecularly reactive strategy to convert copper precursors to metallic copper at <150°C.
  • Employed catechol-based ligands for copper reduction and surface passivation.
  • Investigated the stability of flexible copper under various corrosive conditions.
  • Achieved flexible copper with low resistivity and exceptional stability (>1000 hours in acid, >200 hours in sulfide, >240 hours at 140°C).
  • Surface passivation was effective in enhancing corrosion resistance while maintaining conductivity.

Abstract

Copper’s exceptional electrical and thermal conductivities make it essential for electronics and energy systems. However, oxidation and corrosion limit its long-term reliability, and existing protection strategies often involve high-temperature or multistep processing. We report a molecularly reactive strategy that converts copper precursors to metallic copper at 1000 hours in acid, >200 hours in sulfide, >240 hours at 140°C). This strategy resolves the long-standing trade-off between conductivity, corrosion resistance, and processability for next-generation flexible electronics and energy systems.

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Cite This Study

Zhang et al. (2026) studied this question.

synapsesocial.com/papers/6a080acea487c87a6a40cce1https://doi.org/10.1126/science.aed4488
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