Optical pulse propagation in metal nanoparticle chain waveguides

Finite-difference time-domain simulations show direct evidence of optical pulse propagation below the diffraction limit of light along linear arrays of spherical noble metal nanoparticles with group velocities up to 0. 06c. The calculated dispersion relation and group velocities correlate remarkably well with predictions from a simple point-dipole model. A change in particle shape to spheroidal particles shows up to a threefold increase in group velocity. Pulses with transverse polarization are shown to propagate with negative phase velocities antiparallel to the energy flow.