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May 19, 2026Inorganic Chemistry2 citations

Rational Design of Single-Atom Alloy Catalysts from PtAu 24 Nanoclusters toward Enhanced Electrochemical Activity

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XZXia ZhouSZShenzhi ZhangLQLubing Qin

Key Points

  • This research aims to enhance the electrochemical activity of single-atom alloy catalysts by exploring their design and optimization.
  • Analyzed the catalytic performance of single-atom-doped bimetallic catalysts.
  • Investigated the impact of Pd substitution on oxygen species binding during the oxygen reduction reaction.
  • Demonstrated that the Sabatier optimum is approached for oxygen reduction reactions with optimal design.
  • Found that Pd substitution leads to overbinding of oxygen species, reducing catalytic activity.

Abstract

approaches the Sabatier optimum for the oxygen reduction reaction (ORR), whereas Pd substitution induces overbinding of *O species, leading to diminished catalytic activity. This work provides fundamental insights into the design of single-atom-doped bimetallic catalysts and offers a viable strategy for improving the electrocatalytic performance.

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Cite This Study

Zhou et al. (2026) studied this question.

synapsesocial.com/papers/6a0bfd7a166b51b53d378c51https://doi.org/10.1021/acs.inorgchem.6c00288
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