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September 12, 2012Advanced Materials211 citations

N‐Type Colloidal‐Quantum‐Dot Solids for Photovoltaics

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DZDavid ZhitomirskyMFMelissa FurukawaJTJiang Tang

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Abstract

N-type PbS colloidal-quantum-dot (CQD) films are fabricated using a controlled halide chemical treatment, applied in an inert processing ambient environment. The new materials exhibit a mobility of 0.1 cm(2) V(-1) s(-1) . The halogen ions serve both as a passivating agent and n-dope the films via substitution at surface chalcogen sites. The majority electron concentration across the range 10(16) to 10(18) cm(-3) is varied systematically.

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Zhitomirsky et al. (2012) studied this question.

synapsesocial.com/papers/6a0cce5a9d761985b14a4e42https://doi.org/10.1002/adma.201202825
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