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May 20, 2026Journal of the American Chemical Society9 citations

Deciphering Competitive Kinetics in Nitrate Reduction via Mechanistic Modeling: Impact of Ru and Pd Dopants on Reaction Selectivity

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BLBo LiCCCheng ChenOPOuwen Peng

Key Points

  • The aim is to understand how different dopants affect the kinetics and selectivity of nitrate reduction reactions.
  • Characterization of electrocatalysts using quantitative modeling to identify kinetic bottlenecks.
  • Evaluation of Ru and Pd dopants on reaction mechanisms and selectivity during nitrate reduction.
  • Identified specific kinetic bottlenecks affecting nitrate reduction.
  • Demonstrated that Ru and Pd dopants significantly influence reaction selectivity.

Abstract

characterization with rigorous quantitative modeling, this work provides a predictive blueprint for diagnosing kinetic bottlenecks and accelerating the rational design of highly selective electrocatalysts.

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Cite This Study

Li et al. (2026) studied this question.

synapsesocial.com/papers/6a0d5064f03e14405aa9c1fbhttps://doi.org/10.1021/jacs.6c05585
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