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July 2, 1948Proceedings of the Royal Society of London A Mathematical and Physical Sciences114 citations

Self-consistent field, with exchange, for nitrogen and sodium

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DHD. R. HartreeWHW. Hartree

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Abstract

Abstract Wave functions for the normal configurations of neutral nitrogen and N- have been calculated by the method of the self-consistent field with exchange (Fock’s equations). To the accuracy of the approximation represented by these equations, the N- ion would be unstable and liable to auto-ionization, but it is estimated that a better approximation of the treatment of a many-electron atom would give a small positive ionization potential for N-. Revised wave functions for Na+ and the normal state of neutral Na have also been calculated. Tables of results are given.

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Cite This Study

Hartree et al. (1948) studied this question.

synapsesocial.com/papers/6a0fb87d4fb650da4ffe6fb5https://doi.org/10.1098/rspa.1948.0047
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