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November 9, 2002Journal of the American Chemical Society181 citations

Novel 1,4-Palladium Migration in Organopalladium Intermediates Derived from o-Iodobiaryls

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MCMarino A. CampoRLRichard C. Larock

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Abstract

A novel 1,4-palladium migration in organopalladium intermediates derived from o-iodobiaryls has been observed under modified Heck reaction conditions. This migration process can be switched "on" or "off" by simply choosing the appropriate reaction conditions.

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Campo et al. (2002) studied this question.

synapsesocial.com/papers/6a14b0738c41faed776bf079https://doi.org/10.1021/ja027548l
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