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May 26, 2026Minerals0 citationsOpen Access

Geochemistry and Geological Significance of the Granite Porphyry in the Dulong Sn Polymetallic Deposit, Southeastern Yunnan, China

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XLXin LiZKZhigang KongYWYu Wang

Key Points

  • The study aims to clarify the geochemistry and geochronological characteristics of granite porphyry related to the Dulong S/Zn polymetallic deposit.
  • Zircon U-Pb dating conducted using LA-ICP-MS to determine the age of the granite porphyry.
  • Whole-rock geochemistry and Sr-Nd-Hf isotopic analyses performed to assess the granite's composition and origin.
  • Comparative analysis with multi-phase Laojunshan granites to contextualize findings.
  • Granite porphyry dated to 85.1 ± 1.2 Ma (Late Cretaceous).
  • Notable enrichment of Rb, U, and Ta, with depletions in Ba, Sr, Nb, and Eu, indicating an S-type granite affinity.
  • High concentrations of Sn, W, Zn, and Cu in the granitic melt suggest significant mineralization potential.

Abstract

The giant Dulong Sn-Zn polymetallic deposit, located in the eastern part of the southeastern Yunnan metallogenic belt, is a world-class ore system. Despite extensive research on the source of tin and its mineralization processes, the specific ore-related intrusion and the source of copper remain highly debated. Recent deep exploration has revealed a deep-seated granite porphyry, yet its geochronological and geochemical characteristics, along with its genetic link to mineralization, are poorly constrained. This study presents new zircon U-Pb age, whole-rock geochemistry, and Sr-Nd-Hf isotopic compositions of this granite porphyry, integrated with a regional comparison to multi-phase Laojunshan granites. LA-ICP-MS zircon U-Pb dating yields a Late Cretaceous age of 85.1 ± 1.2 Ma. The Dulong granite porphyry is strongly peraluminous and high-K calc-alkaline to shoshonitic, exhibiting typical S-type granite affinities with enrichment in Rb, U, and Ta, as well as depletions in Ba, Sr, Nb, and Eu. Isotopic signatures (εNd(t) = −12.5 to −12.0, tDM2(Nd) = 1.87 to 1.91 Ga; zircon εHf(t) = −10.24 to −1.44, tDM2(Hf) = 1.24 to 1.79 Ga) suggest that the parental magma was derived from the partial melting of ancient crust, with possible minor input of mantle-derived components in an extensional tectonic setting. The Dulong granite porphyry represents a moderate-to-high temperature, reduced, and highly evolved magmatic system. Notably, its high concentrations of Sn, W, Zn, and Cu indicate that the parental melt was metal-rich, possessing potential for Sn and Cu mineralization. Accordingly, future exploration should prioritize areas characterized by well-developed granite porphyry dykes, skarn–wallrock contact zones, and deep-seated structural intersections.

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Cite This Study

Li et al. (2026) studied this question.

synapsesocial.com/papers/6a153a2eb5d9c58d83e8cfaahttps://doi.org/10.3390/min16060567
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