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May 26, 2026Baghdad Science Journal0 citationsOpen Access

Adsorption and Kinetic Study of Toxic Dye (Methylene Blue) Removal from Simulated Industrial Wastewater Using Sustainable Material

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ZOZahraa H. ObaidJSJasim M. SalmanAOA Nasrollahi Omran

Key Points

  • The study aimed to evaluate the effectiveness of modified Ziziphus spina Christi as an adsorbent for removing methylene blue dye from industrial wastewater.
  • Conducted batch experiments varied by contact times (10-180 minutes), dye concentrations (10-60 mg/L), temperatures (25-60°C), pH (5-9), and adsorbent dosages (0.25-2 g).
  • Characterized ZSC using scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR).
  • Analyzed adsorption kinetics revealing a pseudo-first-order model with a correlation coefficient of 0.969.
  • Achieved a maximum methylene blue removal efficiency of 97.51% at 10 mg/L concentration, 1.5 g adsorbent, pH 8, 50°C, and 60 minutes contact time.
  • Notable performance was found with a particle size of 0.075 μm and stirring speed of 150 rpm.

Abstract

Water pollution is a global issue that affects both human health and the environment. The increasing use of the methylene blue (Mb) dye in various industrial applications poses significant risks. The study aimed to use hydrochloric acid-modified Ziziphus Spina Christi powdered leaves (ZSC) as an effective and low-cost adsorbent for removing Mb dye from effluents. Batch experiments were conducted with contact times of 10–180 minutes, initial dye concentrations of 10–60 mg/L, temperatures of 25–60°C, pH values of 5–9, and sorbent dosages of 0.25-2 g per 40 ml of dye solution. The results showed that the highest removal efficiency of Mb dye was 97.51% using an initial concentration of 10 mg/L, 1.5 g of adsorbent, pH 8, at 50 °C, a contact time of 60 minutes, a particle size of 0.075 μ m, and a stirring speed of 150 rpm. The ZSC was characterized using SEM and FTIR techniques, and the adsorption kinetics were found to follow the pseudo-first-order model, with a correlation coefficient of 0.969. In general, the modified ZSC is an auspicious, friendly, and cost-effective adsorbent for removing Mb dye from aqueous solutions.

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Cite This Study

Obaid et al. (2026) studied this question.

synapsesocial.com/papers/6a153a88b5d9c58d83e8d16ahttps://doi.org/10.21123/2411-7986.5287
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