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September 28, 1981Physical Review Letters308 citations

Quantum Theory of Activated Events in Condensed Phases

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PWPeter G. Wolynes

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Abstract

The quantum analog of Kramers's classical theory of the rate of activated events is presented. By means of a path-integral approach, the correlation function expression for the rate of barrier crossing by a quantum mechanical particle coupled to a heat bath is evaluated for finite temperatures. Tunneling effects are dramatically diminished by the frictional influence of the heat bath.

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Peter G. Wolynes (1981) studied this question.

synapsesocial.com/papers/6a169bd97d286b2899b25e23https://doi.org/10.1103/physrevlett.47.968
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