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May 6, 2008Angewandte Chemie International Edition908 citations

α‐MnO2 Nanowires: A Catalyst for the O2 Electrode in Rechargeable Lithium Batteries

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ADAurélie DébartAPAllan J. PatersonJBJianli Bao

Key Points

  • To evaluate the catalytic performance of alpha-MnO2 nanowires in porous composite oxygen cathodes for high-capacity rechargeable lithium batteries.
  • Fabricated a porous composite oxygen positive electrode using alpha-MnO2 nanowires and carbon.
  • Characterized electrode morphology and discharge product accumulation using scanning electron microscopy.
  • Achieved higher battery storage capacity by incorporating alpha-MnO2 nanowires as the oxygen cathode catalyst.
  • Confirmed the accumulation of lithium peroxide (Li2O2) deposits within the porous alpha-MnO2 and carbon cathode matrix during discharge.

Abstract

Higher-capacity lithium batteries can be fabricated by using α-MnO2 nanowires as the catalyst in a porous, composite oxygen cathode. In the depicted scanning electron micrograph of a composite positive electrode, deposits of Li2O2, which accumulates during discharge, can be seen within a porous matrix consisting of α-MnO2 and carbon. Supporting information for this article is available on the WWW under http: //www. wiley-vch. de/contents/jc₂002/2008/z705648ₛ. pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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Cite This Study

Débart et al. (2008) studied this question.

synapsesocial.com/papers/6a1d1d5bfeb402ac612f2fdehttps://doi.org/10.1002/anie.200705648
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