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December 20, 2002Molecular Physics20 citationsOpen Access

Rotational viscosities of Gay-Berne mesogens

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ACAlejandro CuetosJIJaroslav IlnytskyiMWMark R. Wilson

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Abstract

Rotational viscosities γ1 are calculated for three Gay-Berne models for a wide range of state points in the nematic phase. There was a strong density dependence in the results, with γ1 increasing with increasing density. Away from the clearing point, the temperature dependence of γ1 was described by simple Arrhenius-like behaviour. A comparison of the values of γ1 and the Arrhenius activation energies with real mesogens pointed to a number of problems with the Gay-Beme potential, when used as a model for real mesogenic systems.

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Cuetos et al. (2002) studied this question.

synapsesocial.com/papers/6a2032a75a40e2199cd8dc31https://doi.org/10.1080/0026897021000028410
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