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Terminal transition-metal nitrides are key intermediates in dinitrogen activation and nitrogen-transfer chemistry and have therefore long attracted considerable attention. Despite the intensive work on Cr(V/VI) nitrides in the past, systematic investigations on Cr(IV) nitrides remain lacking. Herein, we report the synthesis and characterization of a Cr(IV) nitride, [Cp*Cr
Chen et al. (2026) studied this question.