A Cross-Scale Review of Thermodynamics-Dominated Cavitation and Failure Mechanisms in Liquid Hydrogen Pumps

The wide application of liquid hydrogen as a key energy carrier is severely limited by the reliability of high-pressure and low-temperature pumps. The traditional research on liquid hydrogen pumps relies on empirical analysis of isolated components, but fails to reveal the fundamental failure mechanism of these pumps. This review argues for a paradigm shift in the understanding and design of liquid hydrogen pumps. We systematically decomposed the failure of the liquid hydrogen pump into a thermodynamic-driven, cross-scale cascading process rather than the failure of isolated components. At the molecular level, the extreme thermal physical properties of liquid hydrogen (ultra-low latent heat and surface tension) can lead to widespread nucleation under slight thermal disturbances. At the mesoscopic scale, the initial perturbation is significantly amplified through the nonlinear dynamics of bubble clusters. This amplification is characterized by intense collapse and strong energy concentration due to the low density and low viscosity of liquid hydrogen. At the component level, this enhanced destructive energy will cause faults similar to phase transitions; namely, the liquid lubrication in the bearings will disappear, the seals will shift from viscous blockage to gas diffusion, and at the same time, the damage caused by low-temperature hydrogen cavitation and corrosion to the materials will also occur simultaneously. At the system level, the strong dynamic coupling among the subsystems has led to a nonlinear performance collapse. This cross-scale failure chain reveals the flaws in the classical cavitation theory, which is based on the assumptions of isothermal and inertia dominance. We have expounded the thermodynamic-dominated cavitation state in liquid hydrogen. This state is quantified by the Σ parameter and governs the multimodal behavior of low-temperature cavitation phenomena. To address this complexity, we have proposed a comprehensive framework that integrates multi-scale collaborative simulation and digital twin, combining molecular dynamics, CFD, system dynamics, and targeted experiments. This review proposes a candidate physical framework for addressing the reliability challenges of liquid hydrogen pumps. It also provides a clear roadmap for the next generation of inherently robust cryogenic fluid machinery, and offers a reference for the design of energy systems under other extreme conditions.