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December 14, 1981Physical Review Letters169 citations

Model of the Neutral-Ionic Phase Transformation

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JHJohn P. HubbardJTJ. B. Torrance

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Abstract

A model is presented describing how an organic solid transforms between a neutral and an ionic ground state. Whereas for a one-dimensional stack this transition is expected to be first order, the Coulomb interactions between stacks can cause the phase transition to occur over a broad temperature range by stabilizing an intermediate region in between the neutral and ionic phases, in which both neutral and ionized species coexist, as observed in tetrathiafulvalene-chloranil.

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Cite This Study

Hubbard et al. (1981) studied this question.

synapsesocial.com/papers/6a231a1a3c6dd25ddfc4528dhttps://doi.org/10.1103/physrevlett.47.1750
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