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October 23, 2019Angewandte Chemie International Edition151 citations

Merging Photocatalysis with Electrochemistry: The Dawn of a new Alliance in Organic Synthesis

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LCLuca CapaldoLQLorenzo L. QuadriDRDavide Ravelli

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Abstract

The merging of a homogeneous photocatalytic system with an electrochemical cell, having exchanged electrons as the only common point, has been recently demonstrated. This combination opens unexplored pathways in synthesis and allowed net-oxidative photocatalytic processes to be realized in the absence of a chemical oxidant, including: 1) the C-H alkylation of heteroarenes and 2) the coupling of azoles with arenes in the presence of an electrogenerated photocatalyst.

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Capaldo et al. (2019) studied this question.

synapsesocial.com/papers/6a24a1270bce2e0489863e43https://doi.org/10.1002/anie.201910348
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