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January 1, 2004Chemical Communications177 citations

Electrochemical reduction of an imidazolium cation: a convenient preparation of imidazol-2-ylidenes and their observation in an ionic liquid

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BGBrian GorodetskyTRTaramatee RamnialNBNeil R. Branda

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Abstract

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride is reduced electrochemically and chemically to produce a nucleophilic carbene, namely 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene. The carbene was also shown to be compatible with and persistent in the ionic liquid tetradecyl(trihexyl)phosphonium chloride.

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Gorodetsky et al. (2004) studied this question.

synapsesocial.com/papers/6a5e60e0520935359de067d2https://doi.org/10.1039/b407386j
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