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January 1, 2010Chemical Communications218 citations

Nickel-catalyzed, sodium iodide-promoted reductive dimerization of alkyl halides, alkyl pseudohalides, and allylic acetates

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MPMichael R. PrinsellDEDaniel A. EversonDWDaniel J. Weix

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Abstract

The first general method for the reductive dimerization of alkyl halides, alkyl mesylates, alkyl trifluoroacetates, and allylic acetates is reported which proceeds with low catalyst loading (0.5 to 5 mol%), generally high yields (80% ave yield), and good functional-group tolerance.

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Prinsell et al. (2010) studied this question.

synapsesocial.com/papers/6a6a6f7eff619b1ab2cb1fc5https://doi.org/10.1039/c0cc01716g
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