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January 19, 2024Organic Letters6 citations

Self-Assembly of Functionalized Twistarenes into Supramolecular Assemblies with Chiroptical Property and Photoconductive Behavior

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ZQZewei QiSWSujuan WangBJBingliang Ji

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Abstract

A pair of novel chiral 1-phenylethylamine-modified twistarenes ( 4 and 11; compound 4 = 9,14-di- tert -butyl-7,16-diphenyl-2-(1-phenylethyl)-1 H -benzo8',9'triphenyleno2',3':6,7fluoreno2,1,9- def isoquinoline-1,3(2 H )-dione) have been synthesized and characterized, and how the solvent component affects the chirality transfer of their self-assembled processes is investigated in mixtures with THF and H 2 O. The ordered assembly of 11 exhibits circular dichroism response. In addition, both 11a and 11b display positive photoconducting behavior.

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Cite This Study

Qi et al. (2024) studied this question.

synapsesocial.com/papers/6a71518dce524a4339c4e141https://doi.org/10.1021/acs.orglett.3c03854
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