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May 4, 2004Science541 citationsOpen Access

Infrared Spectroscopic Evidence for Protonated Water Clusters Forming Nanoscale Cages

MMMitsuhiko MiyazakiAFAsuka FujiiTETakayuki Ebata

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Abstract

Size-dependent development of the hydrogen bond network structure in large sized clusters of protonated water, H+(H2O)n (n = 4 to 27), was probed by infrared spectroscopy of OH stretches. Spectral changes with cluster size demonstrate that the chain structures at small sizes (n less, similar 10) develop into two-dimensional net structures (approximately 10 /= 21).

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Cite This Study

Miyazaki et al. (2004) studied this question.

synapsesocial.com/papers/6a719c50a528af2d65c424d3https://doi.org/10.1126/science.1096037
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