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December 13, 2003Journal of the American Chemical Society231 citations

A New Reaction Sequence Involving Palladium-Catalyzed Unsymmetrical Aryl Coupling

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FFFiorenza FacciniEMElena MottiMCMarta Catellani

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Abstract

Biphenylylalkenes containing an ortho substituent in one ring and a different ortho-, meta-, or para-substituent in the other are prepared in satisfactory yield from an ortho-substituted aryl iodide, an ortho-, meta-, or para-substituted aryl bromide, a terminal olefin, and a base in DMF under the joint catalytic action of palladium(0) and norbornene.

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Cite This Study

Faccini et al. (2003) studied this question.

synapsesocial.com/papers/6a71c7bc26a7f98052ddf8a9https://doi.org/10.1021/ja039043g
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