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May 1, 1977Journal of the American Chemical Society132 citations

Solvent effects and their relation to the E and C equation

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RDRussell S. DragoLPLynne Burton ParrCCCraig S. Chamberlain

Key Points

  • To examine the influence of solvent media on the parameters and thermodynamic predictions of the dual-parameter E and C equation.
  • Evaluated thermodynamic data for Lewis acid-base adduct formation across varying solvent conditions.
  • Assessed electrostatic (E) and covalent (C) parameters to account for non-specific and specific solvent interactions.
  • Solvent interactions significantly alter experimental enthalpies of adduct formation relative to gas-phase or nonpolar baselines.
  • The E and C equation framework can accommodate solvent perturbation effects when solvent-solute competitive equilibria are explicitly factored in.

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolvent effects and their relation to the E and C equationRussell S. Drago, Lynne Burton Parr, and Craig S. ChamberlainCite this: J. Am. Chem. Soc. 1977, 99, 10, 3203–3209Publication Date (Print):May 1, 1977Publication History Published online1 May 2002Published inissue 1 May 1977https://pubs.acs.org/doi/10.1021/ja00452a001https://doi.org/10.1021/ja00452a001research-articleACS PublicationsRequest reuse permissionsArticle Views283Altmetric-Citations126LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

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Cite This Study

Drago et al. (1977) studied this question.

synapsesocial.com/papers/6a8362f6c5c429e4bdeefbe4https://doi.org/10.1021/ja00452a001
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