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April 30, 2001Advanced Synthesis & Catalysis119 citations

Asymmetric Hydrogenation of Ketones with Polymer-Bound BINAP/Diamine Ruthenium Catalysts

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TOTakeshi OhkumaHTHiroshi TakenoYHYuji Honda

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Abstract

The BINAP/1,2-diphenylethylenediamine RuCl2 complexes bound to a polystyrene resin act as precatalysts for asymmetric hydrogenation of various simple ketones. The enantioselectivity, turnover number, and turnover frequency are comparable to those attained under homogeneous conditions.

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Ohkuma et al. (2001) studied this question.

synapsesocial.com/papers/6a8b0d9095f0361a9ebeadbfhttps://doi.org/10.1002/1615-4169(20010430)343:4<369::aid-adsc369>3.0.co;2-3
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