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A review describing a series of (mostly accidental) intriguing reactions of silicone grease with various highly polar organometallic reagents is presented. The products are unusual and unexpected (sometimes supramolecular) compounds, incorporating various fragments of the parent polysiloxane chain, such as disiloxane or other oligosiloxane units, (OSiMe 2 ) n O ( n = 2, 3, etc.), dimethylsilanone Me 2 SiO, dimethylsilylene Me 2 Si, and other methylsilicon moieties.
Ionel Haiduc (2003) studied this question.