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January 1, 2008Dalton Transactions33 citations

A simple entry into nido-C2B10 clusters: HCl promoted cleavage of the C–C bond in ortho-carboranyl diphosphines

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JCJ.P.H. CharmantMHM.F. HaddowRMR. Mistry

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Abstract

Treatment of the diphosphines ortho-B10H10C(P(t)Bu2)C(PR2) (R = Et, Cy, Ph) with HCl gives the zwitterionic, nido-12-vertex species B10H10C(PH(t)Bu2)C(PClR2); these reactions are reversed by the addition of NEt3.

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Cite This Study

Charmant et al. (2008) studied this question.

synapsesocial.com/papers/6a90e70171e842060670fa50https://doi.org/10.1039/b719404h
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