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November 1, 2007The Journal of Organic Chemistry35 citations

Oppenauer Oxidation of Secondary Alcohols with 1,1,1-Trifluoroacetone as Hydride Acceptor

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RMRossella MelloJMJaime Martı́nez-FerrerGAGregorio Asensio

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Abstract

1,1,1-Trifluoroacetone (2a) reacts as a hydride-acceptor in the Oppenauer oxidation of secondary alcohols (1) in the presence of diethylethoxyaluminum. The oxidant allows for selective oxidation of secondary alcohols in the presence of primary alcohols.

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Mello et al. (2007) studied this question.

synapsesocial.com/papers/6a9140f2a84e863524465efahttps://doi.org/10.1021/jo7016422
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