January 1, 1976Journal of the Chemical Society Dalton Transactions12 citations

Nuclear magnetic resonance measurement of sulphur inversion barriers in mer-trisbis(trimethylsilylmethyl) sulphidetrichloro-rhodium(III) and -iridium(III)

EAE. W. Abel GFGraham W. Farrow KOKeith G. Orrell

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Abstract

Variable-temperature 1H n. m. r. studies of mer-RhCl3S (CH2SiMe3) 23 and mer-IrCl3S (CH2SiMe3) 23 have yielded slightly different sulphur inversion barriers for the two different sulphide ligand environments in these complexes. In both complexes the barrier is somewhat lower for the sulphide ligand trans to chloride.

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Abel et al. (1976) studied this question.

synapsesocial.com/papers/6a954e676d8ecf100b25e4b7 https://doi.org/10.1039/dt9760001160

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January 1, 1976Journal of the Chemical Society Dalton Transactions12 citations

Nuclear magnetic resonance measurement of sulphur inversion barriers in mer-trisbis(trimethylsilylmethyl) sulphidetrichloro-rhodium(III) and -iridium(III)

View Full Paper

EAE. W. Abel GFGraham W. Farrow KOKeith G. Orrell

Key Points

Key points are not available for this paper at this time.

Abstract

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Cite This Study

Abel et al. (1976) studied this question.

synapsesocial.com/papers/6a954e676d8ecf100b25e4b7 https://doi.org/10.1039/dt9760001160

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