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The oxygen evolution reaction (OER), a crucial semireaction in water electrolysis and rechargeable metal–air batteries, is vital for carbon neutrality. Hindered by a slow proton-coupled electron transfer, an efficient catalyst activating the formation of an O–H bond is essential. Here, we proposed a straightforward one-step hydrothermal procedure for fabricating PO43–-modified NiFe layered double-hydroxide (NiFe LDH) catalysts and investigated the role of PO43– anions in enhancing OER. Phosphate amounts can efficiently regulate LDH morphology, crystallinity, composition, and electronic configuration. The optimized sample showed a low overpotential of 267 mV at 10 mA cm–2. Density functional theory calculations revealed that intercalated and surface-adsorbed PO43– anions in NiFe LDH reduced the Gibbs free energy in the rate-determining step of *OOH formation, balancing oxygen-containing intermediate adsorption/dissociation and promoting the OER. Intercalated phosphate ions accelerated precatalyst dehydrogenation kinetics, leading to a rapid reconstruction into active NiFe oxyhydroxide species. Surface-adsorbed PO43– interacted favorably with adsorbed *OOH on the active Ni sites, stabilizing *OOH. Overall, the synergistic effects of intercalated and surface-adsorbed PO43– anions significantly contributed to enhanced OER activity. Achieving optimal catalytic activity requires a delicate equilibrium between thermodynamic and kinetic factors by meticulously regulating the quantity of introduced PO43– ions. This endeavor will facilitate a deeper comprehension of the influence of anions in electrocatalysis for OER.
Ding et al. (Fri,) studied this question.