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In low-permeability reservoirs, strong molecular interactions exist at the solid-liquid interface, necessitating the overcoming of the threshold pressure gradient in shale oil extraction. A profound comprehension of molecular interactions between oil and reservoir matrix is crucial to develop a productive strategy for enhanced oil recovery. Molecular dynamics simulation has become an important method for analyzing microscopic mechanisms of some static properties and dynamic processes. In this study, a molecular model of shale oil was built based on the reported experimental results and simulation. Subsequently, the molecular model was utilized to build a flow model within three matrix pores: kerogen, quartz, and portlandite. A comprehensive analysis of the interfacial effects and size effects on the threshold pressure gradient was undertaken. Emphasis was placed on elucidating the influence of the adsorption behaviors (stable adsorption, unstable adsorption, non-adsorption) of polar components at the interface on the flow of shale oil. The utilization of the critical shear stress facilitated the accurate prediction of the threshold pressure gradient of shale oil within large pores. Moreover, within the context of the flow model of shale oil in nanoscale pores, we conducted some explorations into oil displacement by CO2. This work suggests fresh ideas for studying the oil-matrix interactions on the nanoscale and provides theoretical guidance for shale oil exploitation.
Cui et al. (Fri,) studied this question.