Stabilisation and characterisation of a trinuclear uranyl complex by ligand-radical formation

Key Points

• The research aims to explore how redox-active ligands influence the stabilization and properties of trinuclear uranyl complexes.
• Synthesis of a trinuclear uranyl complex using specific redox-active ligands.
• Characterization of the complex through various analytical techniques.
• Investigation of the electronic properties and redox pathways.
• Stabilization of the uranyl complex was successfully achieved through ligand-radical formation.
• Modification of electronic properties of the complex was observed.
• Alternative redox reaction pathways were suggested based on the ligand interactions.