Cross-Electrophile Stannylation of Alkyl Triflates and Halides with Chlorostannanes Enabled by Cr(II)-Phenanthroline Catalysis

Key Points

• Investigate the potential of Cr(II)-phenanthroline catalysis in cross-electrophile stannylation.
• Utilized chlorostannanes for stannylation of alkyl triflates and halides.
• Applied Cr(II)-phenanthroline as a catalyst to facilitate the reaction.
• Enhanced formation of carbon-metal bonds was observed.
• Successful coupling of various alkyl electrophiles was achieved.