In this paper, a novel symmetrical three-wavelength toggling archetype for measuring the concentration of gases using a tunable diode laser absorption spectroscopy (TDLAS) system is introduced and demonstrated. The system was operated at 1.5714 µm with a 2 kHz update rate, targeting an absorption line of gaseous CO2. Precompensated diode–current pulses are introduced to offset the inherent thermal time constants of the diode laser by orders of magnitude. Here, repetition rates matching that of contemporary methods can be achieved, while simultaneously providing a noteworthy wavelength stability of 0.6 pm for the three targeted wavelengths that are approximately 70 pm apart (142 pm maximum wavelength excursion). A 10 Hz current loop locks one of the wavelengths to a CO2 absorption peak, thus providing an absolute and stable wavelength reference. The flexibility in choosing the shape and repetition frequency of the current pulses makes this approach easily adaptable to other gases and/or absorption lines, since wavelength filters are avoided. The new method is benchmarked against a two-wavelength precompensated continuous-wave TDLAS technique, revealing a fourfold improvement in reproducibility with system restart over the span of 24 days, while outperforming other widespread spectroscopic techniques applied to comparable transmittance levels. The effect of the analytical model was further studied by thermally inducing baseline changes, showing a 7.9 ± 0.2 times weaker correlation between concentration and temperature with respect to the one observed using the two-wavelength TDLAS archetype. These results demonstrate the system’s suitability for sensitive applications.
Zanetti et al. (Tue,) studied this question.