Structures and electronic properties of transition metal regulated 3-connectivity for metal cluster-based covalent organic frameworks

Key Points

• Enhanced electronic properties are observed due to the regulation of 3-connectivity through transition metals, and different metal clusters displayed varied impacts.
• Notably, the study identifies distinct electronic behaviors for different configurations, with promising results for conductive applications in materials.
• Assessing the structural frameworks utilizing a combination of metal clusters and covalent organic frameworks reveals systematic enhancements in stability and functionality.
• Findings highlight the versatility of transition metal incorporation in tailoring cluster properties for advanced applications in nanotechnology and materials engineering.