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Herein, we for the first time report a reversible conversion between green-emissive DMPZMnCl4 and red-emissive DMPZ4(MnCl6)(MnCl4)2·(H2O)2 (DMPZ = 1,4-dimethylpiperazine) using kinetic and thermodynamic controlling strategies. Significantly, the synchronous structural and emission transformations in single-component organic manganese halides with adjustable emission colors are highlighted.
Liu et al. (Sun,) studied this question.