This study evaluates engine performance and emission characteristics of diesel/biodiesel/HVO blends (biodiesel: 0–30% vol., HVO: 10% vol.). Results demonstrate significant reductions: PM2.5 (12.5–43.9%), CO (8.01–24.5%), SO₂ (7.69–25.9%), and NOx (3.33% reduction via HVO addition). Metal emissions (Na/Fe/Ca/Al > 80% of total detected metals) decreased by 24.3–26.8%, while brake-specific fuel consumption (BSFC) improved by 2.21%. Electron paramagnetic resonance (EPR) spectroscopy revealed consistent PM2.5 microstructural properties across blends (g-factor: 2.0033–2.0035), though radical concentrations (3.0 × 1018-7.4 × 1018 spins/g) exceeded ambient levels by 10-fold. Raman analysis confirmed invariant carbon nanostructures (D/G band ratio: 0.910–0.943), indicating fuel composition primarily modulates emission quantity rather than particulate quality. These findings establish HVO-biodiesel blends as effective fossil diesel alternatives, warranting further research on environmentally persistent free radicals (EPFRs).
Cheng et al. (Thu,) studied this question.