Electric vehicles are becoming more common daily because countries are moving towards net-zero emissions. Different generations of NMC battery cells are used for EV applications. This work investigates the degradation behavior of high-energy 75 Ah prismatic NMC631 lithium-ion cells using a combined incremental capacity analysis (ICA) and electrochemical impedance spectroscopy (EIS) framework under different conditions. Cells are cycled at an identical C-rates and depths of discharge (DoD), and at different temperatures to systematically evaluate the impact of temperature on electrochemical aging. ICA results revealed that cells cycled at low temperatures maintain stable peaks and a high SoH (>90%) after completing 1600 full equivalent cycles (FECs). EIS analysis confirms the distinct impedance evolution patterns. Degradation mode analysis is performed using the ICA, and EIS highlights the combined evolution of conductivity loss, loss of lithium inventory, and loss of active material. It also highlights different degradation path trajectories under identical operating conditions stem from the progressive amplification of internal cell heterogeneities during aging. The results demonstrate that combining ICA and EIS provides complementary insights into degradation evolution and enables clear differentiation between gradual aging and sudden failure pathways in high-energy NMC cells.
Raza et al. (Thu,) studied this question.