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A Tunable Charge-Transfer-State Rotaxane Gated by Solvent, Anions, and Aggregation | Synapse

April 29, 2026Physical Chemistry Chemical Physics0 citations

A Tunable Charge-Transfer-State Rotaxane Gated by Solvent, Anions, and Aggregation

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WHWei-Liang HuAnhui Normal University YYYuan YuanAnhui Normal University GWGui‐Yuan WuAnhui Normal University

Key Points

To explore a method for the precise regulation of charge-transfer states in interlocked systems.
Developed a triple-stimuli strategy for rotaxane systems
Investigated effects of solvent, anions, and aggregation on charge transfer
Analyzed ultrafast dynamics of the system
Demonstrated enhanced control over charge-transfer states
Achieved regulation through multiple stimuli combinations
Revealed insights into the ultrafast dynamics behavior

Abstract

Precise multi-stimuli regulation of intramolecular charge-transfer (CT) states in mechanically interlocked systems is challenging due to the complexities of synergistic control and unresolved ultrafast dynamics. We report a triple-stimuli strategy...

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Cite This Study

Hu et al. (Thu,) studied this question.

synapsesocial.com/papers/69f154a4879cb923c4944d4b https://doi.org/https://doi.org/10.1039/d6cp00972g