January 1, 2015

Transition from ZIF-L-Co to ZIF-67: a new insight into the structural evolution of zeolitic imidazolate frameworks (ZIFs) in aqueous systems

JZJingcheng ZhangZhejiang Chinese Medical University TZTianci ZhangNorth China Electric Power University DYDongbo YuKunming University of Science and Technology

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Abstract

A leaf-like ZIF-L-Co is synthesized for the first time and the molar ratio of Hmim/Co plays an important role in the synthesis. ZIF-L-Co is a transient phase at the initial stage of ZIF-67 crystal growth. The crystallization process of ZIF-67 from ZIF-L-Co follows a solid transformation mechanism.

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Zhang et al. (Thu,) studied this question.

synapsesocial.com/papers/69f7a4e654dd77bf6fbf87bb https://doi.org/https://doi.org/10.1039/c5ce01531f

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